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Glutathione: The Ultimate Antioxidant for Your Health

The initial step for the de nov o synthesis of GSH occurs through the activity of glutamate-cysteine ligase, a heterodimer of a catalytic subunit and a modifier subunit that catalyses the first and rate-limiting step to form the dipeptide γ-glutamylcysteine from cysteine and glutamate (Reference Desideri, Ciccarone and Ciriolo27)

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In contrast to spontaneous hepatocellular foci of alteration and neoplasms, foci and tumors induced by peroxisome proliferators are negative for γ-glutamyl transpeptidase and placental glutathione-S transferase (Evans and Lake 1998)